catena-Poly[[triaquachlorido-μ3-malonato-cerium(III)] hemihydrate]
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چکیده
منابع مشابه
catena-Poly[[triaquachlorido-μ3-malonato-cerium(III)] hemihydrate]
The asymmetric unit of the title compound, {[Ce(C(3)H(2)O(4))Cl(H(2)O)(3)]·0.5H(2)O}(n), contains a Ce(3+) atom coordinated by a chloride anion, three water mol-ecules and a malonate ligand, and one water mol-ecule of crystallization with a factor of occupancy of 50%. The malonate ligand is bonded to three different symmetry-related metal atoms yielding a one-dimensional coordination polymer ru...
متن کاملcatena-Poly[[triaquamagnesium]-μ2-malonato]
In the title compound, [Mg(C3H2O4)(H2O)3] n , the metal atom is in an octa-hedral environment. The octa-hedra are connected by malonate anions, forming chains along the c-axis direction. O-H⋯O hydrogen bonds link these chains into a three-dimensional network.
متن کاملPoly[[aquadi-μ3-malonato-hexaphenylditin(IV)] acetone solvate]
The asymmetric unit of the title polymeric complex, {[Sn(2)=(C(6)H(5))(6)(C(3)H(2)O(4))(H(2)O)]·C(3)H(6)O}(n), comprises of two Sn cations, one malonate anion and a non-coordinating acetone solvent mol-ecule. Both crystallographically independent Sn cations are five-coordinated by two O and three C atoms in a distorted trigonal-bipyrimidal geometry. One of the Sn cations is bridged by the malon...
متن کاملcatena-Poly[[aquadioxidouranium(VI)]-μ3-4,4′-oxydibenzoato]
The title compound, [UO(2)(C(14)H(8)O(5))(H(2)O)](n), is a polymeric UO(2) complex bridged by 4,4'-oxydibenzoate ligands. One carboxyl-ate group of the bridging ligand chelates a uranyl cation while the other carboxyl-ate group of the ligand bridges two other two uranyl cations, forming a double-chain polymeric structure. The central U(VI) atom is seven-coordin-ated in a distorted UO(7) penta-g...
متن کاملPoly[[aqua-μ6-benzene-1,2,3-tricarboxylato-μ3-hydroxido-dizinc] hemihydrate]
In the title compound, {[Zn(2)(C(9)H(3)O(6))(OH)(H(2)O)]·0.5H(2)O}(n), there are three independent Zn(II) atoms present; two are located on special positions, viz a twofold rotation axis and an inversion centre, and the third is located in a general position. The Zn(II) atom on the inversion centre is six-coordinated by four O atoms from four different benzene-1,2,3-tricarboxyl-ate anions and t...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s1600536810044727